I intend to offer a series of posts designed to explain the sometimes bewildering complexity of Molten Salt Reactor Technology. This first post explains two nuclear fuel breeding cycles.

Rather than offering a single potential reactor design, the Molten Salt Reactor (MSR) idea offers a large number of design options, each of which would require a significant amount of research, before a prototype reactor could be built. The Molten Salt Reactor designer is faced with a bewildering number of elective choices, each offering a set of advantages and disadvantages. Each choice that the designer makes will dictate a number of design features some of which require further choices.

Lets start with nuclear fuel. My father first demonstrated that not only U-235 but also Pu-239 could be used as a reactor fuel in MSRs. During the ORNL Molten Salt Reactor experiment Oak Ridge scientists tested the use of the three fissionable materials that can be used as nuclear fuels, Plutonium-239 (Pu-239), Uranium-235 (U-235) and Uranium-233 (U-233). Once during the operation of the Molten Salt Reactor Experiment (MSRE) they used all three potential fuels in the reactor at the same time.
Of the three potential fuels, U-233 had some significant advantages. Neither U-235 nor Pu-239 produced enough neutrons per neutron hit, to support breeding more nuclear fuel at a slow (thermal) neutron speed range. U-233, produced by breeding thorium did produce enough neutrons to breed thorium at a slow temperature range. We will see that this offers a very large advantage. U-235 is not efficiently produced by breeding, while Pu-239 can only be produced in the breeding range with fast neutrons.
Breeding means that for every fuel atom used in the nuclear process, at least one new fuel atom is produced. Thus in a plutonium fast breeder, if a neutron strikes a plutonium atom, it is very likely to fission into two smaller atoms, almost always with three neutrons left over. Those neutrons will be moving fast and will contain a lot of energy. Fast neutrons are more likely to produce fission in plutonium atoms than slow neutrons. Neither U-235 nor Pu-239 produce enough neutrons to maintain breeding if they encounter a slow (also called thermal) neutron. Thus Plutonium can only be produced as a nuclear fuel in so called fast reactors. There are, as we shall see, some major disadvantages to fast reactors.
Fast reactors are often thought of as having liquid sodium as their coolant, although liquid lead, and a liquid lead-bismuth mixture have also been used as a coolant in fast reactors. In addition it is possible to build fast Molten Salt Reactors. The stability of Molten Salt Reactor operations in enhanced by Xenon-135 removal. Xenon-135 is a radioactive gas that is a byproduct of nuclear fission and has a very large neutron cross section. Because it is very likely to capture neutrons, Xenon-135 can adversely effect a chain reactor in a reactor. Thus it would be highly desirable to get Xenon-135 out of a reactor core quickly after it is produced. That is impossible in a solid core reactor, but it is not difficult to do in a Molten Salt Reactor. The presence of Xenon-135 adversely effects to the ability of reactors to breed nuclear fuel, so any MSR that is designed as a thorium breeder would have a system for moving Xenon-135 out of its core.

There are decided advantages for fuel reprocessing with MSRs. Compare the fuel reprocessing technique for a Molten Salt Reactor with the fuel reprocessing technique proposed for the Integral Fast Reactor (IFR) a LMFBR. In two fluid MSR, the blanket salt flows out of the blanket, and protactinium and U-233 are withdrawn from it by chemical processes. Once they are processed out of the carrier salt, the U-233 is re-fluoridated and returned to the core. The protactinium is set aside until it undergoes a nuclear transformation to U-233, and then that U-233 is returned to the core. In a IFR, the spent fuel is fished out of the reactor core, and once recovered, dumped into a molten salt bath, in which it dissolves. Then by use of electroplating, various material from the old fuel, for example plutonium, are separated out of the bath, and deposited on electrodes. Eventually the separated metal, is recovered, melted and mixed into an alloy, which is then cooled enough to serve as fuel elements, and then returned into the reactor. The MSR fuel reprocessing technology is much simpler than the fuel reprocessing technology designed for the IFR.

In addition fast reactors require 10 times as much nuclear fuel to produce a chain reaction as thermal breeder reactors. It does not really matter if the fast reactor is cooled by liquid metal of liquid salts, a fast breeder reactor just needs a who lot more fuel in order to operate than a thermal breeder reactor does. This makes fast reactors poor candidates to replace fossil fuels like coal with nuclear power, because many reactors will have to be built quickly, and fueling enough fast reactors quickly will be a big challenge.

There are two breeding cycles, the Uranium 238 breeding cucle, and the thorium 232 breeding cycle. Both cycles have some advantage. Plutonium-239 produces more neutrons per fission event than thorium, but fewer fission events per neutron in the thermal spectrum. In fact Pu-239 produces so many fewer fission events in the thermal spectrum than in the fast spectrum, that it is impossible to achieve a positive breeding ratio for the U-238/Pu-239 breeding cycle in a thermal reactor. On the other nand U-233 produces about as many neutrons per fission event in the thermal range as in the fast range, and about as many fission events. That means that the Th-232/U-233 breeding cycle is as effective in the thermal range asin the fast range, and because thorium breeding only requires about 10% of the nuclear fuel in the thermal range as U-238 breeding requires in the fast range, thorium breeding cycle reactors can be deployed far faster.

In addition Liquid fuel reactors have advantages over solid fuel reactors. Once a sollid fuel is inserted into a reactor it almost always stayes there for a year or more, while fission products build up in the fuel. We have already seen that Xenon-135 becomes a reactor control problem, although Xenon-135 eventually reaches an equalibrium because of its short half-life. The presence of Xenon-135 in a nuclear core, can interfear with a reactor's capacity to bread, especially in the thermal breeding range. Thus Thorium fuel cycle breeder reactor are better candidates for rapid deployment than U-238 fuel cycle breeders, and liquid fuel thorium breeding reactors have advantages as solid fuel thorium breeder. Liquid fueled thorium breeders, as we have already noted, have advantages over solid fuel U-238 breeders. Thus the Thorium fuel cycle Molten Salt Reactor (often called the LFTR) would seem to offer several advantages over U-238 fuel cycle liquid metal fast reactor.

In the next post of this series I intend to explain the difference between single fluid and twoi fluid Molten Salt Reactors.